Comparison of the reactivities of 2-mercaptoaniline and 2-hydroxyaniline with 2-chloronicotinoyl chloride

Authors: De Souza, M.V.N.; Vasconcelos, T.R.A.; Wardell, S.M.S.V.; Wardell, J.L.; Carvalho, E.M. Source: Journal of Sulfur Chemistry (Print), v. 27, n.3, p. 193-202, 2006. Publisher: Taylor & Francis Group Abstract The reaction between equimolar 2-chloronicotinoyl chloride and 2-mercaptopyridine in ClCH2CH2Cl, after 30 minutes refluxing in ClCH2CH2Cl solution, produced pyrido[2,3,b][1,5]benzothiazepin-5(H)one 7, and 6-[3-(2-benzothiazolyl)pyridin-2-yl)thio]-N-[3-(2-benzothiazolyl)pyridin-2-yl]aniline 8. In contrast, […]