(2 S ,3 R )- tert -Butyl N -[4-( N -benzyl-4-fluorobenzenesulfonamido)-3-hydroxy-1-phenylbutan-2-yl]carbamate

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Abstract

In the title mol­ecule, C₂₈H₃₃FN₂O₅S, the mean plane about the tertiary amine group (sum of the angles subtended at the sp²-hybridized N atom = 359.7°) forms a dihedral angle of 16.66 (6)° with the phenyl ring adjacent to the carbamate group. The sulfonamide benzene ring and the hy­droxy group lie to either side of the C₂NS plane, whereas the benzyl­phenyl (connected to the N atom) and carbamate substituents lie to the other side. Supra­molecular layers propagating in the ac plane are found in the crystal, linked by hy­droxy-sulfonamide O-HO and carbamate-carbamate N-HO hydrogen bonds along with C-HO and C-H inter­actions.

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Keywords: None Document Type: Research Article DOI: http://dx.doi.org/10.1107/S1600536812011440 Publication date: 21 de Março de 2012