Authors: Tiekink, E.R.T.; Wardell, S.M.S.V.; Wardell, J.L.; Ferreira, M.L.; De Souza, M.V.N.; Kaiser, C.R.
Source: Acta Crystallographica. Section E, v. 68, p. 1850-1851, 2012.
Publisher: International Union of Crystallography
Abstract
In the title hydrated salt, C16H13ClN3+·Cl–·2H2O, a small twist is evident in the cation so that the chlorobenzene ring is not coplanar with the central hydrazinyl group [the N-C-C-C torsion angle = -4.8 (12)°]. The conformation about the imine N=C bond [1.284 (10) Å] is E. The components of the structure are connected into a three-dimensional architecture via O-H
O, O-HCl and N-HCl hydrogen bonds. One water H atom is disposed over two sites of equal occupancy.
Keywords: None Document Type: Research Article DOI: http://dx.doi.org/10.1107/S1600536812022660 Publication date: 1 de Janeiro de 2012
