Benzyl N-[(S)-2-hy­droxy-1-({[(E)-2-hy­droxy-4-meth­oxy­benzyl­idene]hydrazin­yl}carbon­yl)eth­yl]carbamate

---

Abstract

The shape of the title compound, C₁₉H₂₁N₃O₆, is curved with the conformation about the imine bond [1.291 (3) Å] being E. While the hy­droxy-substituted benzene ring is almost coplanar with the hydrazinyl residue [N-N-C-C = 177.31 (18)°], an observation correlated with an intra­molecular O-HN hydrogen bond leading to an S(6) ring, the remaining residues exhibit significant twists. The carbonyl residues are directed away from each other as are the amines. This allows for the formation of O-HO and N-HO hydrogen bonds in the crystal, which lead to two-dimensional supra­molecular arrays in the ac plane. Additional stabilization to the layers is afforded by C-H inter­actions.

---

Keywords: None Document Type: Research Article DOI: http://dx.doi.org/10.1107/S1600536810047720 Publication date: 1 de Janeiro de 2010