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Four nitrobenzaldehyde isonicotinoylhydrazones at 120K: four different supramolecular strucutures in two and three dimensions

Authors: De Souza, M.V.N.; Wardell, J.L.; Wardell, S.M.S.V.; Low, J.N.


Abstract

The mol­ecules of 2-nitro­benzaldehyde iso­nicotinoyl­hydra­zone, C13H10N4O3, (I), are linked into a three-dimensional framework by a combination of one N-H...N and three C-H...O hydrogen bonds. In the isomeric compound 3-nitro­benzaldehyde iso­nicotinoyl­hydrazone, (II), the mol­ecules are linked into complex sheets by a combination of three hydrogen bonds, one each of the N-H...N, C-H...N and C-H...O types. The mol­ecules of the third isomer, namely 4-nitro­benzaldehyde iso­nicotinoyl­hydrazone, (III), are linked into bilayers by a combination of one N-H...N, one C-H...N and two C-H...O hydrogen bonds. 2,4-Dinitro­benzaldehyde iso­nicotinoyl­hydrazone, (IV), crystallizes as a stoichiometric monohydrate, C13H9N5O5·H2O, and the mol­ecular components are linked into a three-dimensional framework by a combination of O-H...O, O-H...N, N-H...O and three independent C-H...O hydrogen bonds.
Keywords: None Document Type: Research Article DOI: http://dx.doi.org/10.1107/S0108270105032580 Publication date: 1 de Janeiro de 2005

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